Jeremy Corbyn says he is seeking a "constructive alternative" to the PM's deal, in order to prevent a no-deal Brexit.
The Labour leader was speaking after meeting the EU's chief Brexit negotiator, Michel Barnier, for talks in Brussels.
It comes ahead of an EU summit where Theresa May will ask EU leaders to postpone Brexit for three months.
Mr Corbyn said he did not believe the PM's deal "is a way forward".
"We are therefore looking at alternatives, and building a majority in Parliament that can agree on a future constructive economic relationship with the European Union," he told reporters after the meeting.
Mr Corbyn was joined by shadow Brexit secretary Sir Keir Starmer for the talks, which also included European Commission Secretary-General Martin Selmayr.
He is also expected to meet seven European leaders at the two-day summit, which begins later.
Mr Corbyn has faced criticism after walking out of a Brexit meeting with the PM on Wednesday because Labour defectors, who are now members of the Independent Group, turned up.
Independent Group spokesman Chuka Umunna described the Labour leader's behaviour as "juvenile" at a time of national crisis.
After the meeting, other opposition party leaders said they were unimpressed with what they heard from the prime minister.
Mr Corbyn said there had been "a confusion" over the meeting, and he had held separate discussions with Mrs May later on.
"I'm also arranging to meet the prime minister next week again on a one-to-one basis," he added.
Labour has backed an extension of Brexit talks to find an alternative to the prime minister's deal which will command a majority in the Commons.
On Wednesday, Brexit Secretary Stephen Barclay said Labour's plans were "not credible", and the party was asking for "things that are simply not on offer".
Latest Stories
-
Brassier scores winner for Brest as they edge Rennes to secure European football
7 mins -
‘What are the real causes of the erratic power outages?’ GUTA demands from ECG
29 mins -
Implementing ESG framework in Ghana’s energy sector for sustainability
1 hour -
CAFCC: Dreams FC exit competition after 3-0 defeat in Kumasi
1 hour -
The detrimental effects of political interference on Ghana’s electricity sustainability
1 hour -
Prof. Opoku-Agyemang’s appointment as running mate intimidates the NPP – Benjamin Quashie
1 hour -
Black Stars physical trainer dead
1 hour -
Bawumia to kick off nationwide campaign for Election 2024 tomorrow
1 hour -
GUTA charges ECG to provide ‘dumsor’ timetable for businesses to plan
1 hour -
Reason for training professional counsellors is to heal a hurting world – CCP president
4 hours -
Woman allegedly brings dead man to bank to take out a loan
4 hours -
It’s a good feeling to score against PSG because I’m a Marseille boy – Andre Ayew
4 hours -
Joe Lartey Sr: A voice that brought life to Ghana sports and beyond
5 hours -
Bawumia promises to tackle issue most dear to Ghanaians as he begins nationwide campaign
6 hours -
Indian couple donate $24m fortune to charity to adopt monkhood
6 hours