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Thousands of Thais have packed Bangkok streets to see a convoy carrying the body of King Bhumibol Adulyadej.
The convoy passed through the capital to the royal palace as mourners wept and held up portraits of the late king. Millions watched live on TV.
Crown Prince Maha Vajiralongkorn has been named as successor, but has asked for a delay in the process.
The death of the world's longest-reigning monarch sparked an outpouring of grief in Thailand.
Official mourning will last a year. The cabinet declared Friday a government holiday, and flags are to fly at half-mast for the next 30 days.
People have been asked to wear black, and avoid "joyful events" during this period. Cinema screenings, concerts and sports events have been cancelled or postponed.
News websites have turned their pages black and white. All television channels in Thailand aired state media programmes including live coverage of the day's events.
Image copyrightEPA
Image captionThousands lined the streets awaiting the king's funeral procession
Image copyrightEPA
Image captionHe served as a unifying figure and his loss is being mourned across Thailand
Image copyrightREUTERS
Image captionThailand's Princess Maha Chakri Sirindhorn travelled with the body
The crown prince travelled in the convoy carrying the king's body, which will lie at a temple in the Royal Palace while people pay their respects.
It could be months before the late king's cremation.
"This is the worst loss in my life," said one of those lining the streets.
Later on Friday, the Crown Prince conducted the bathing ceremony of the king's body, a traditional Thai Buddhist funeral rite.
Revered figure
The king had been ill for a long time. When news of his death was announced on Thursday evening, many in the large crowds outside the hospital where he died broke down.
King Bhumibol was widely respected across Thailand, and thought of by many as semi-divine.
He earned the devotion of Thais for his efforts to help the rural poor, including agricultural development projects and works of charity.
Image copyrightGETTY IMAGES
Image captionNewspapers have turned their pages black and white
Image copyrightREUTERS
Image captionFlags are to fly at half mast for 30 days
Image copyrightREUTERS
Image captionThe official mourning period will last a year
The monarch was also seen as a stabilising figure in a country often wracked by political turmoil.
Thailand remains under military rule following a coup in 2014.
The country has suffered from political violence and upheaval over the past decade, as well as a long-running Muslim separatist insurgency in the southern provinces which sees regular small-scale bomb attacks.
Though a constitutional monarch with limited official powers, many Thais looked to King Bhumibol to intervene in times of high tension. He was seen as a unifying and calming influence through numerous coups and 20 constitutions.
However, his critics argued he had endorsed military takeovers and at times had failed to speak out against human rights abuses.
Heir's challenge
The crown prince, who is 64, is much less well known to Thais and has not attained his father's widespread popularity. He spends much of his time overseas, often in Germany.
While Thai Prime Minister Prayuth Chan-ocha has said the crown prince will ascend the throne next, there is uncertainty over when that will happen after the prince asked for a delay in succession.
Profile: Crown Prince Vajiralongkorn
Image copyrightAFP
Image captionMost ordinary Thais know only a few details about Crown Prince Vajiralongkorn
Privy Council President Prem Tinsulanonda, a 96-year-old former prime minister, has been named regent in line with the constitution.
He remains as regent until the Thai assembly invites the heir to succeed to the throne, the Bangkok Post reported.
Strict lese-majeste laws protect the most senior members of Thailand's royal family from insult or threat. Public discussion of the succession can be punishable by lengthy jail terms.
Given the pivotal role the king has played in maintaining the balance of power in Thailand's volatile political environment, the succession will be a formidable challenge for the government, says the BBC's Jonathan Head in Bangkok.

Image captionThe royal family tree
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