Arsenal will take on Rennes in the Europa League round of 16, while Chelsea will face Dynamo Kiev.
Slavia Prague will meet five-time winners Sevilla, while Valencia, who beat Celtic in the round of 32, take on Krasnodar.
The first leg will take place on March 7, with the return fixture a week later on March 14.
DRAW IN FULL
- Chelsea v Dynamo Kiev
- Eintracht Frankfurt v Inter
- Dinamo Zagreb v Benfica
- Napoli v Salzburg
- Valencia v Krasnodar
- Sevilla v Slavia Prague
- Arsenal v Rennes
- Zenit St Petersburg v Villarreal
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