Barcelona have been drawn against Inter Milan and Borussia Dortmund in the Champions League group stages.
The three former champions have been drawn together in tough-looking Group F which also include the Czech Republic's Slavia Prague.
Champions League holders Liverpool have been drawn to play Napoli once more in the group stages.
2018/19 runners-up Tottenham will face Bayern Munich in Group B, as well as Olympiacos and Crzena Zvezda.
Eye-catchingly, PSG and Real Madrid are both in Group A, Atletico face their nemesis Cristiano Ronaldo and Juventus in Group D.
Europa League winners Chelsea will play against last season's semi-finalists Ajax in Group H, as well as Valencia and Lille.
Salzburg and Genk will also play Liverpool in Group E.
The first round of matches will take place on the 17/18 September, with the last games of the groups to be played on 10/11 December.
Finalised groups for the 2019-20 Champions League:
Group A: PSG, Real Madrid, Club Brugge, Galatasaray
Group B: Bayern Munich, Tottenham, Olympiacos, Red Star Belgrade
Group C: Manchester City, Shakhtar Donetsk, Dinamo Zagreb, Atalanta
Group D: Juventus, Atletico Madrid, Bayer Leverkusen, Lokomotiv Moscow
Group E: Liverpool, Napoli, Red Bull Salzburg, Genk
Group F: Barcelona, Borussia Dortmund, Inter, Slavia Prague
Group G: Zenit, Benfica, Lyon, RB Leipzig
Group H: Chelsea, Ajax, Valencia, Lille
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