Audio By Carbonatix
Barcelona lost an eight-goal thriller as Villarreal struck twice deep into stoppage time to leave Xavi's side 10 points off the top of La Liga.
The hosts had fought back with three goals in 11 minutes to lead after trailing 2-0 until the hour mark.
But Villarreal equalised with six minutes remaining and Alexander Sorloth put the visitors back in front in the ninth minute of stoppage time.
Jose Luis Morales then added a fifth after 102 minutes to seal victory.
Defeat leaves defending champions Barcelona third in the La Liga title race, 10 points behind leaders Real Madrid and eight points off Girona in second.
It comes after they were knocked out of the Copa del Rey quarter-finals in a 4-2 defeat by Athletic Bilbao on Wednesday.
It is Barcelona's third loss in five matches, with their other defeat in that run coming against Real Madrid in the Spanish Super Cup, which they lost 4-1.
After Gerard Moreno's first-half opener and Ilias Akhomach's 54th-minute goal, Barcelona produced a stunning comeback through Ilkay Gundogan, Pedri and an Eric Bailly own-goal.
But, following Goncarlo Guedes' 84th-minute equaliser for Villarreal, the hosts were left exposed in their pursuit of a late winner and ultimately punished by Sorloth's and Luis Morales' late goals.
Real Madrid came from behind to beat Las Palmas 2-1 on Saturday and moved back above Girona, who play struggling Celta Vigo on Sunday (13:00 GMT).
Latest Stories
-
Starting a business in Ghana as a young man is tough – HR practitioner
3 minutes -
Nkrumah’s policies should inform Ghana’s development — UG African Studies Director
6 minutes -
Ghana Evangelical Missions Association urges Christian leaders to preach against galamsey and intensify advocacy
13 minutes -
Buipe Hausa Festival: National President Tafida calls for vigilance, unity, and youth reform
15 minutes -
Government urges domestic airlines to reduce airfares after duty exemptions
17 minutes -
Beyond vehicle age: Why Ghana needs a smarter vehicle import policy
38 minutes -
Are we marketing Ghana before fixing the experience? A hard question for our tourism ambition
42 minutes -
AFCON 2027Q: Prince Adu Kwabena major doubt for Ghana after head injury
44 minutes -
Government to procure furniture to help more SHSs move from double-track — Haruna Iddrisu
50 minutes -
Adutwum spokesperson alleges ‘turf war’ between Education Ministry and GES over Free SHS
52 minutes -
Black Stars: Adu Kwabena a doubt for September-October games after head injury
1 hour -
Fire guts four-bedroom apartment at Millennium City
1 hour -
KMA seeks funding to restart stalled Kumasi Central Market Phase II project
1 hour -
Government unveils new guidelines to improve regulation of non-profit organisations
2 hours -
Annoh-Dompreh cautions against partisan application of law in political speech cases
2 hours